Chemicals in food

Chemicals in food

  • Chemicals are added to food for their preservation, enhancing their appeal, and adding nutritive value in them. Main categories of food additives are as follows:
  • Food colours
  • Flavours and sweeteners
  • Fat emulsifiers and stabilising agents
  • Flour improvers - antistaling agents and bleaches
  • Antioxidants
  • Preservatives
  • Nutritional supplements such as minerals, vitamins and amino acids.

Different types of food additives:

Artificial sweetener agent

  • They are synthetic sugar substitutes but may be derived from naturally occurring substances, including herbs or sugar itself. They are also known as intense sweeteners because they are sweeter than regular sugar.
  • Usually they don't have calories.

Sweeteners

Relative sweetness to sugar

Uses

Saccharin

 

  • Ideal for tabletop
  • use and dissolves easily in liquids
  • maintains sweetness at any temperature, meaning you can freeze or bake with it

Aspartame

200

  • Mainly used as a tabletop sweetener to replace sugar
  • Loses sweetness when heated, thus useful in frozen and uncooked desserts

Sucralose

 

600

  • Maintains sweetness when heated, making it popular to bake with

 

  • Doesn't raise insulin levels so popular among diabetics

Alitame

2000

  • Alitame is high potency sweetener, although it is more stable than aspartame, the control of sweetness of food is difficult while using it.

 

Food preservatives:

  • Chemical substances which are added to food material to prevent their spoilage due to microbial growth.
  • Examples – Sugar, Salts, Sodium benzoate
  • Artificial food preservatives may act as antioxidants, They make the food more acidic.
  • They reduce the moisture level of the food.
  • They slow down the ripening process and they prevent the growth of microorganisms.

Food colours: Substances added to food to increase the acceptability and attractiveness of the food product. Examples – Allura Red AC, Tartrazine

Nutritional supplements: Substances added to food to improve the nutritional value. Examples -Vitamins, minerals etc.

Fat emulsifiers and stabilizing agents: Substances added to food products to give texture and desired consistency. Examples – Egg yolk (where the main emulsifying chemical is Lecithin)

Antioxidants: Substances added to food to prevent oxidation of food materials. Examples – ButylatedHydroxy Toluene (BHT), ButylatedHydroxy Anisole (BHA).

Cleansing Agents

The word detergent means cleansing agent. Actually detergent word is derived from Latin word „detergere‟ means “to wipe off”, Cleansing agents are the substance which remove dirt and have cleansing action in water. These are also called surfactants.

Detergents can be classified into two types.

1. Soapy detergents or soaps, and

2. Non-soapy detergents or soapless soap.

Soaps :

  • These are sodium or potassium salts of higher fatty acids.
  • They are prepared by saponification of glycerides.

Saponification :

  • Saponification is the process of making soap from alkali and fat.
  • Vegetable oils and animal fats are fatty esters in the form of triglycerides.
  • The alkali breaks the ester bonds and releases the fatty acid salt and glycerol.
  • If necessary, soaps may be precipitated by salting out with saturated sodium chloride.

 

Structure of soap :

 

 

Types of soaps 

Toilet soap 

Toilet soaps are prepared by using better grades of fats and oils and care is taken to remove excess alkali. Colour and perfumes are added to make these more attractive.

Medicated soap 

In medicated soaps, substances of medicinal value are added. In some soaps, deodorants are added.

Shaving soap 

Shaving soaps contain glycerol to prevent rapid drying. A gum called, rosin is added while making them. It forms sodium resinate which lathers well.

Laundry soap 

Laundry soaps contain fillers like sodium resinate, sodium silicate, borax, and sodium carbonate.

Transparent soap 

Transparent soaps are made by dissolving the soap in ethanol and then evaporating the excess solvent.

 

Soapless Soap/Synthetic Detergents

Synthetic detergents are sodium salts of alkylbenzene sulphonic acids. They are better cleansing agents than soap.

These are of three types:

  • (i) Anionic detergents: These detergents are the sodium salts of sulfonated long-chain alcohols. These long-chain alcohols are treated with concentrated sulphuric acid to form alkyl hydrogen sulfates. Now, these alkyl hydrogen sulfates are neutralized by treating with alkali and thus form anionic detergents.


    (ii) Cationic detergents: These detergents are the quaternary ammonium salts of amines. In the molecules of these detergents, the cationic part has a long chain of hydrocarbon and a positive charge on the nitrogen atom. One of the important cationic detergents is cetyltrimethylammonium bromide.

    (iii) Non-ionic detergents: These are the detergents that do not contain any kind of ion on them. These detergents are formed by the reaction of stearic acid with polyethylene glycol.

    These detergents remove grease and oil by micelle formation.

 

  • Biodegradable detergents: Detergents having straight hydrocarbon chains that are easily decomposed by microorganisms. Example: Sodium lauryl sulphate
  •  
  • Non-Biodegradable detergents: Detergents having branched hydrocarbon chains that are not easily decomposed by microorganisms.

 

Difference between soaps and detergents-

Soap

Detergents

Soaps are sodium salts of long-chain carboxylic acids. 

Detergents are sodium salt of long-chain benzene sulphonic acids. 

The ionic group in soap is COONa

The ionic group in detergents is 

Soaps have a relatively weak cleansing action. 

Detergents have strong cleansing action. 

They cannot be used effectively in hard water as they produce scum i.e., insoluble precipitates of Ca2+, Mg2+, Fe2+ etc. 

They are effective in soft, hard or saltwater. 

Soaps are biodegradable. 

Some of the detergents are non-biodegradable.

 

Advantages of synthetic detergents over soaps

1. Synthetic detergents can be used even in case of hard water whereas soaps fail to do so.

2. Synthetic detergents can be used in the acidic medium while soaps cannot because of their hydrolysis to free acids.

3. Synthetic detergents are more soluble in water and hence, form better lather than soaps.

4. Synthetic detergents have a stronger cleansing action than soaps.